Removal of Diclofenac-Na from aqueous solution onto H3PO4 modified composite clay

  • Ayobami Olu Ajani Department of Chemical Engineering, Ladoke Akintola University of Technology, Ogbomoso, Nigeria; Bioenvironmental, Water and Engineering Research Group (BWERG), Ladoke Akintola University of Technology, Ogbomoso, Nigeria https://orcid.org/0000-0003-2148-6014
  • Ademola Toheeb Adeniji Department of Chemical Engineering, Ladoke Akintola University of Technology, Ogbomoso, Nigeria; Bioenvironmental, Water and Engineering Research Group (BWERG), Ladoke Akintola University of Technology, Ogbomoso, Nigeria; Department of Chemistry, Universidade do Porto, Porto, Portugal https://orcid.org/0000-0002-8049-1537
  • Samson Shina Ayodabo Department of Chemical Engineering, Ladoke Akintola University of Technology, Ogbomoso, Nigeria; Bioenvironmental, Water and Engineering Research Group (BWERG), Ladoke Akintola University of Technology, Ogbomoso, Nigeria https://orcid.org/0000-0003-0210-0470
  • Abass Olanrewaju Alade Department of Chemical Engineering, Ladoke Akintola University of Technology, Ogbomoso, Nigeria; Bioenvironmental, Water and Engineering Research Group (BWERG), Ladoke Akintola University of Technology, Ogbomoso, Nigeria; Science and Engineering Research Group (SAERG), Ladoke Akintola University of Technology, Ogbomoso, Nigeria https://orcid.org/0000-0003-4837-3685
  • Tinuade Jolaade Afolabi Department of Chemical Engineering, Ladoke Akintola University of Technology, Ogbomoso, Nigeria; Bioenvironmental, Water and Engineering Research Group (BWERG), Ladoke Akintola University of Technology, Ogbomoso, Nigeria https://orcid.org/0000-0001-9618-0226
  • Sofiat Ololade Ganiyu Department of Chemical Engineering, Ladoke Akintola University of Technology, Ogbomoso, Nigeria; Bioenvironmental, Water and Engineering Research Group (BWERG), Ladoke Akintola University of Technology, Ogbomoso, Nigeria https://orcid.org/0000-0002-4808-4528
DOI: https://doi.org/10.15328/cb1274
Keywords: bentonite-kaolinite-worm cast clay, composite, Diclofenac-Na, geosorption, wastewater

Abstract

Under batch experiment conditions, this work seeks to successfully remove Diclofenac-Na (DCF-Na) from an aqueous solution utilizing a composite sorbent made of Bentonite, Kaolinite clay, and Worm casting (BKW). This study investigated the structural modification of the H3PO4 Modified Clay by X-ray fluorescence and the effect of selected adsorption factors – DCF-Na concentration and modified BKW composite dosage. The concentration equilibrium data was used to study six isotherm models. Freundlich isotherm model better explained the adsorption of DCF-Na onto modified BKW composite with a correlation coefficient close to 1. Kinetics models were examined, and the Elovich model gave a better fit than other kinetic models studied. Mass diffusion mechanisms and thermodynamics studies were successfully carried out. The enthalpy change values evaluated were negative, which revealed the spontaneity of DCF-Na remediation onto modified BKW, and that DCF-Na adsorption is exothermic and occurred through a physisorption process.

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Published
2022-08-16
How to Cite
Ajani, A., Adeniji, A., Ayodabo, S., Alade, A., Afolabi, T., & Ganiyu, S. (2022). Removal of Diclofenac-Na from aqueous solution onto H3PO4 modified composite clay. Chemical Bulletin of Kazakh National University, 106(3), 20-35. https://doi.org/https://doi.org/10.15328/cb1274
Issue
Vol 106 No 3 (2022): Chemical Bulletin of Kazakh National University
Section
Environmental Chemistry
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