Properties of langmuir monolayers based on organosoluble cationic polyelectrolyte-anionic surfactant complex and organic dyes

  • E. Seliverstova E.A. Buketov Karaganda State University, Karaganda
  • N. Ibrayev E.A. Buketov Karaganda State University, Karaganda
  • Sarkyt Kudaibergenov Institute of Polymer Materials and Technologies, Almaty
DOI: https://doi.org/10.15328/chemb_2012_329-33
Keywords: Langmuir monolayers, organosoluble complex, nanosized solid films, Langmuir-Blodgett method, polycomplex

Abstract

Phase states of monolayers of organosoluble stoichiometric polycomplex based on cationic polyelectrolyte and anionic surfactant has been studied. Formation of mixed monolayers consisting of polyelectrolyte-surfactant complex (PSC) and dye molecules at water-air interface was shown. Assembling conditions of fluorescent nanosized solid Langmuir-Blodgett (LB) films based on PSC and dyes were defined. It is ascertained that electrostatic interaction between polycomplex and dye molecules is responsible for formation of fluorescing LB films based on molecules of nonamphiphilic organic dyes.

Author Biography

Sarkyt Kudaibergenov, Institute of Polymer Materials and Technologies, Almaty
K.I. Satpaev Kazakh National Technical University, Almaty

References

1. Sergeyev V. G.; Pyshkina O. A.; Lezov A. V.; Mel'nikov A. B.; Ryumtsev E. I.; Zezin A. B.; Kabanov V. A. DNA complexed with oppositely charged amphiphile in low-polar organic solvents // Langmuir. – 1999.-№ 15.-Р. 4434-4440.

2. Ponomarenko E. A.; Tirrell D. A.; MacKnight W. J. Stoichiometric complexes of synthetic polypeptides and oppositely charged surfactants in organic solvents and in the solid state // Macromolecules.-1996.-№29.-Р.8751-875.

3. Acharya S.; Kamilya T.; Sarkar J.; Parichha T. Kr.; Pal P.; Talapatra G.B. Photophysical properties of 4-methyl 3-phenyl coumarin organized in Langmuir–Blodgett films: Formation of aggregates // Materials Chemistry and Physics.-2007.-Vol. 104.-P.88–92.

4. Yeroshina S.A.; Ibrayev N.Kh.; Kudaibergenov S.E.; Rullens F.; Devillers M.; Laschewsky А. Spectroscopic properties of mixed Langmuir–Blodgett films of rhodamine dyes and poly(N;N-diallyl-N-octadecylamine-alt--maleic acid) // Thin Solid Films.- 2008.- Vol.516.-P.2109-2114.

5. Ibrayev N. Kh.; Aimukhanov A. K ; Seliverstova E. V. Interlayer Triplet–Triplet Energy Transfer in Nanosized Molecular Layers // High Energy Chemistry.-2009.-Vol. 43; № 7.-P. 577–581.

6. Trabelsi S.; Guillot S.; Ritacco H.; Boue F.; Langevin D. Nanostructures of colloidal complexes formed in oppositely charged polyelectrolyte/surfactant dilute aqueous solutions // European Physical Journal E.-2007.-№ 23.-P. 305–311.

7. Vaknin D.; Dahkle S.; Travesset A. Induced crystallization of polyelectrolyte-surfactant complexes at the gas-water interface // Physical Review Letters.- 2004.-Vol. 93; № 21.-P. 218302/1-218302/4.

8. Kundu S. Polyelectrolyte–surfactant complexes on solid surface // Journal of Colloid and Interface Science.-2010.- № 344.-P. 547–555.

9. Shpak A. V.; Pirogov A.V.; Shpigun O.A. The selectivity in MEKC of pseudo-stationary phases based on polyelectrolyte complexes: I. Composition of the complex // Analytical and Bioanalytical Chemistry.-2005.-№ 382.-P. 504–512.

10. Cortez M. L.; Gonzalez G. A.; Battaglini F. An Electroactive versatile matrix for the construction of sensors // Electroanalysis.-2011.- Vol. 23; № 1.-P.156 – 160.

11. Taylor D. J.; Thomas F.; Penfold R. K. Polymer/surfactant interactions at the air/water interface // Journal of Advances in Colloid & Interface Science.-2007.-Vol. 132; № 2.-P. 69-110.

12. Zhang X. L.; Taylor D. J. F.; Thomas R. K.; Penfold J. Adsorption of polyelectrolyte/surfactant mixtures at the air−water interface: modified poly(ethyleneimine) and sodium dodecyl sulfate // Langmuir.-2011.-Vol. 27; № 6. P. 2601-2612.

13. Lipptisch M. E.; Draxker S.; Kohker E. Organic materials for non-linear optics; vol.2: UK Society of Chemistry; London; 1991. 89 p.

14. El-Nadi L.; Al-Houty L.; Omar M. M.; Ragab M. Organic thin film material producing novel blue laser // Chemical Physics Letters.- 1998.-Vol. 286.-P. 9-14.

15. Mansour A. F.; Salem A. L.; El-Sayed N. M.: Spectroscopy; photostability and optical efficiently of luminescent solar concentrator // Proceedings Indian Academy of Science. Chemistry.-1998.- Vol. 110.- P. 351-360.

16. Krishna M. M. G. Excited-state kinetics of the hydrophobic probe Nile Red in membranes and micelles // Journal of Physical Chemistry A.-Vol. 19.-P. 3589-3595.

17. Adamson A. Physical Chemistry of Surfaces: A Wiley-Interscience Publication; New York; 1997; 785 p.

18. Арсланов В.В. Полимерные монослои пленки Лэнгмюра-Блоджетт. Полиреакции в организованных молекулярных ансамблях: структурные превращения и свойства // Успехи химии.- 1991.-Т. 60; № 6.- С.1155-1189.

19. Ibraуev. N.Kh.; Alekseeva V. I.; Marinina L. E.; Savvina L. P. The effect of chromophore–chromophore interaction on the spectral luminescent properties of oxazine dye dimmers // Russian Journal of Physical Chemistry A.-Vol. 82; № 5.-P. 860–863.

Published
2012-09-25
How to Cite
Seliverstova, E., Ibrayev, N., & Kudaibergenov, S. (2012). Properties of langmuir monolayers based on organosoluble cationic polyelectrolyte-anionic surfactant complex and organic dyes. Chemical Bulletin of Kazakh National University, 67(3), 29-33. https://doi.org/https://doi.org/10.15328/chemb_2012_329-33
Issue
Vol 67 No 3 (2012): Chemical Bulletin of Kazakh National University
Section
Colloid and Nano Chemistry
Creative Commons License

This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License (CC BY-NC-ND 4.0) that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.