Разработка физико-химических и технологических основ рационального использования ванадий–никель–железо–кальцийсодержащих отходов теплоэлектростанций

T. Krasnenko; T. Sirina; V. Viktorov; M. Rotermel; G. Solovyov

doi:10.15328/chemb_2014_181-93

T. Krasnenko Институт химии твердого тела УрО РАН, г. Екатеринбург
T. Sirina Челябинский государственный педагогический университет, г. Челябинск
V. Viktorov Челябинский государственный педагогический университет, г. Челябинск
M. Rotermel Институт химии твердого тела УрО РАН, г. Екатеринбург
G. Solovyov Челябинский государственный педагогический университет, г. Челябинск

DOI: https://doi.org/10.15328/chemb_2014_181-93

Ключевые слова: ТЭС, шлам химической водоочистки, ванадий-никель-железо-кальцийсодержащие отходы теплоэлектростанций, аттестация шламов, десульфурация отходов ТЭС.

Аннотация

Комплексом исследований физико-химических свойств отходов теплоэлектростанций, сжигающих мазут, фазовых соотношений в модельных системах V₂O₅–NiO(MgO)–CaO–Na₂O и растворимостей основных фаз, образующихся при термообработке, показана возможность их переработки по единой технологической схеме с получением товарных ванадий-, никель- и кальцийсодержащих продуктов.

Литература

1. Sirina T.P., Mizin V.G., Rabinovich E.M. Extraction of vanadium and nickel from waste thermal power plants [Izvlechenie vanadiya I nikelya iz othodov teploelectrostanciy]. Ekaterinburg: UrO RAN, 2001. 338 p .

2. Slobodin B.V., Krasnenko T.I., Dobrynin B.E. Wastes from thermal power plants - industrial raw materials for the extraction of vanadium [Othodi teploelectrostanciy – promishlennoe sir’e dlya izvlecheniya vanadiya]. Metallurg – Metallurgist, 2001. 8. P. 32-35.

3. Complex processing of vanadium raw materials: chemistry and technology [Kompleksnaya pererabotka vanadievogo sir’ya: himiya i tehnologia]. Edited by Mizin V.G., Rabinovich E.M., Sirina T.P. Ekaterinburg: UrO RAN, 2005. – 415 p.

4. Slobodin B.V., Krasnenko T.I., Gorbunova E.M. Regulation of pyrometallurgical processes for extracting vanadium from industrial raw materials on the basis of chemical modeling of vanadium oxide systems [Regulirovanie pirometallurgicheskih processov pri izvlechenii vanadiya iz promishlennogo sir’ya na osnove himicheskogo modelirovaniya oksidnih vanadiyisoderzhashih system]. Metallurg – Metallurgist, 2004. 2. P. 44-48.

5. Slobodin B.V., Krasnenko Т.I., Dobrinin B.Е. Vanadium oxide bronze in system Na2O-CaO-MGO-V2O5 (M = Mg, Ni) [Oksidnie vanadiyevie bronzi v sistemah Na2O–CaO–MO–V2O5 (M = Mg, Ni)]. Jurnal neorgan. himii. – Russian Journal of inorg.chem., 2001. 46, 11. P. 1922 – 1926.

6. Slobodin B.V. Chemical modeling formation of EOD sodium vanadate and the extraction of vanadium from a multi-component material [Himicheskoe modelirovanie obrazovania OVB natria i vanadatov pri izvlechenii vanadiya iz mnogokomponentnogo sirya]. XIII Vserossiskoe soveshanie po visokotemperaturnoi himii silikatov i oksidov (Sankt-Peterburg, 19 – 21 november 2002.): tez. dokl.– Sankt-Peterburg: Institut himii silikatov im. I.V. Grebenshikova RAN, 2002. P. 62.

7. Sirina, Т.P. Studying the interaction of Mg (VO3)2, Mg2V2O7, CaMgV2O7 with solutions of sulfuric acid and sodium hydroxide [Izuchenie vzaimodeistvya Mg(VO3)2, Mg2V2O7, CaMgV2O7 s rastvorami sernoi kisloti i gidroksida natriya] . VI Vsesoiyznoe soveshanie po himii, technologii i primeneniiy vanadiyevih soedinenii (Nijnii Tagil, 16 – 18 may 1990 г.): tez. dokl. Nijnii Tagil , 1990. P. 150 – 153.

8. Sirin А.V., Krasnenko Т.I., Sirina Т.P. Desulphurization of oil – fired thermal power plant ash to form complex vanadium – nickel concentrates [Desulfuracia zol mazutnih teplovih elektrostancii s polucheniem kompleksnih vanadii – nikelevih]. Mejdunarodni simpozium «Poriydok, besporiydok i svoistva oksidov ODPO-2006» (Sochi, 19 – 23 september 2006 g.): sb. tr. – Rostov-on-Don: Publishing House of the Rostov State University Press, 2006. P. 119 - 121.

9. Sirin A.V., Krasnenko T.I., Mizin V.G. Desulphurization of secondary raw vanadium [ Desul’furaciya vtorichnogo vanadievogo sir’ya] . Metallurg – Metallurgist, 2006. 11 .P. 43-46.

10. Krasnenko T.I. The equilibrium phase diagram - the basis of the industrial waste recycling technology [Diagrammi fazovih ravnovessiiy – osnova realizacii tehnologii pererabotki tehnogennih othodov] Izvestiya Rossiiyskoy Akademii Nauk. Seriya fizicheskaya – Bulletin of the Russian Academy of Sciences: Physics, 2010. 74, 8. P. 1217 – 1220.

11. Krasnenko T.I. Environmental resource approach to the processing of industrial waste of oil-fired power plants of Russia [Resursoecologicheskiyi podhod k problem pererabotki tehnogennih othodov mazutnih teploelektrostanciiy Rossii]. All-Russian Conference "Research in the field of processing and recycling of waste and man-made structures" (Еkaterinburg, 24-27 november 2009): tr. All-Russia. Conf. with elements of a school for young scientists. Ekaterinburg, 2009. PP. 94 – 96.

12. Krasnenko T.I. Physical - chemical model to optimize the quality of the environment in the industrial area of thermal power plants [ Fiziko-himicheskaya model’ optimizacii kachestva okruzhaushei sredi v promishlennoy zone teploelectrostanciyi]/ Krasnenko T.I., Bamburov V.G. // Zhurnal «Himicheskaya tehnologiya» - "Chemical Technology" magazine . – 2010. – Т.11, №6. – PP. 380 – 383.

13. Krasnenko T.I. Physico-chemical basis of complex processing of vanadium waste [ Fiziko-himicheskie osnovi kompleksnoy pererabotki vanadiysoderzhashih othodov] Kurnakovskoe IX International Meeting on the physical and chemical analysis: Theses. Reports. [IХ Mezhdunarodnoe Kurnakovskoe soveshanie po fiziko-himicheskomu analizu: tez. dokl]. Per’m, 2010. P. 281.

14. Krasnenko T.I. Complex processing of vanadium-containing waste CHP Urals and Siberia [Kompleksnaya pererabotka vanadiysoderzhashih othodov TEC Urala I Sibiri]. Symposium "Ural Mining School - Region" [Simpozium «Ural’skaya gornaya shkola - regionam»] (Ekaterinburg, 11-12 april 2011 y.): Proceedings. Ekaterinburg, 2011. P. 159 – 160.

15. Bamburov V.G., Lenev D.S., Sirina T.P. Extraction of vanadium and molybdenum concentrates from industrial waste [Izvlechenie vanadiya I molibdena iz koncentratov I tehnogennih othodov]. 14th International Symposium "Order, Disorder and Properties of Oxides ODRO-14" [14-I Mezhdunarodniy simpozium «Poryadok, besporyadok i svoystva oksidov ODRO-14»](p. Lоо, 14 –19 september 2011 y.): Proceedings. Rostov-na- Donu SKNC VSH UFU APSN, 2011. Т. 1. PP. 192 – 194.