Recombination of radiation defects and structure of potassium metaphosphate
Abstract
It is conducted researches recombination luminescence in potassium metaphosphate. It is established that at change of structure type the recombination mechanism changes. In crystal metaphosphate of potassium it hole, in glasslike – electronic. It proves to be true quantum chemical modeling and influence by inpurity manganese ions.
References
1. Лепилина Р.Г., Смирнова Н.М. Термограммы неорганических фосфатных соединений. – Ленинград: Наука, 1984. – 270 с.
2. Kenzi H., Motohiro N., Naoshi K. ESR studies on gamma-irradiated (KPO3)n crystals // Journal of Polymer Science Part A-2: Polymer Physics. - 1970. –Vol.8. - Issue 3. - P. 447 – 453.
3. Yasuo N. Electron Paramagnetic Resonance Spectra of Phosphate Glasses Irradiated with Gamma-rays // Bulletin of the Chemical Society of Japan.- 1964. - Vol.37, №.7. - Р.1089-1090.
4. Hughges W.E., Moulton W.G. New paramagnetic centers in irradiated potassium dihydrogen phosphate // Chem. Phys. – 1963. - Vol.35, №5. – Р.1358-1361.
5. Кларк Р. Компьютерная химия. – М.: ИЛ, 1989. –210 с.
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.
Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License (CC BY-NC-ND 4.0) that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.