Electroanalytical properties of molybdenum electrode and the thermodynamics characteristics of electrode processes at the interphase boundary

  • Dina Mendaliyeva Makhambet Utemisov West Kazakhstan State University, Uralsk
  • Z. Kunasheva Makhambet Utemisov West Kazakhstan State University, Uralsk
  • G. Utepkalieva Makhambet Utemisov West Kazakhstan State University, Uralsk
Keywords: electrode, potential, molybdenum, function, potentiometry, energy of Gibbs, entalpy, entropy

Abstract

The optimal terms for application of molybdenum electrode as an indicatory electrode at the potentiometer measuring were defined. For comparison an industrial platinum electrode was used. Basic electro-analytical properties of electrode in metal salts solutions were found. The ions of metals possess similar electrode functions. The sensitiveness of the investigated electrode is higher than on a platinum electrode. The temperature coefficients of electromotive force on molybdenum electrode were determinated. Thermodynamic characteristics of electrode reaction were calculated.

References

1. Budnikov G.K., Evtjugin G.A., Shajdarova L.G. Scientometric analysis of publications on electrochemical methods of analysis. [Naukometricheskiy analiz publikacy po jelektrohimicheskim metodam analiza]. Mater. mezhd. nauch. konf. «Chemistry, Chemical Engineering and Biotechnology at the Turn of the Millennium». Tomsk, 2006. 1. P. 95 – 100.

2. Budnikov G.K., Maystrenko V.N., Murinov Yu.I. Voltammetry with modified and ultraelektrodami. [Vol'tamperometrija s modificirovannymi i ul'trajelektrodami]. Moscow: Nauka, 1994. 240 p.

3. Shvarcenbah G., Flashka G. Complexometric titrations. [Kompleksonometricheskoe titrovanie] Moscow: Himiya, 1970. 360 p.

Published
2013-09-14
How to Cite
Mendaliyeva, D., Kunasheva, Z., & Utepkalieva, G. (2013). Electroanalytical properties of molybdenum electrode and the thermodynamics characteristics of electrode processes at the interphase boundary. Chemical Bulletin of Kazakh National University, 72(4), 95-102. https://doi.org/https://doi.org/10.15328/chemb_2013_495-102