Obtaining of polystyrene suspensions with given dispersion
Abstract
Polystyrene suspensions were synthesized by emulsion polymerization of styrene in the presence of a small additive (3% by weight) of polymethylmethacrylate (as stabilizer). The additive is not compatible with the formed polystyrene. Formed suspensions have narrow size distribution of the polymer granules with a diameter of 0.3-0.4 microns.
The kinetics of polymerization was studied by dilatometric method. The rate of reaction was determined. Dispersed composition of the polymer suspensions was studied by electrophoretic light scattering. Optimal conditions for obtaining the above mentioned polystyrene suspensions are: monomer/water phase ratio 1:25, initiator concentration 2%, the reaction temperature 70°C.
Obtained polystyrene suspension particles may be used as adsorbent-carriers of various bioligands (live cells, antibodies, viruses) for visualization during the rapid analysis and identification by optical microscopy.
References
1 Krasheninnikova IG, Gritskova IA, Papkov VS (2007) Plastics [Plastmassy] 5:16-18. (In Russian)
2 Stanishevskyi YM, Gritskova IA, Prokopov NI, Ozhehovski A, Lobanov AN (2002) Polymer science Series A [Vysokomolekulyarnye soedineniya. Seriya A] 11:1887-1893. (In Russian)
3 Kulichikhin VG (2012) Workshop on colloidal chemistry [Praktikum po kolloidnoi himyi]. University textbook [Vuzovskyi uchebnik], Moscow, Russia. P.288. ISBN 978-5-9558-0217-6. (In Russian)
4 Kiryutina OP (2008) The study of the initial stage of a heterophase polymerization of styrene [Izuchenie nachalnoi stadyi geterofaznoi polymerizacii stirola]. Abstract of dissertation for Candidate of Chemical Sciences Degree, Moscow, Russia. P.147. (In Russian)
5 Gritskova IA, Prokopov NI, Cherkasov VR (1995) Polymer Science Series A [Vysokomolekulyarnye soedineniya. Seriya A] 7:1156-1159. (In Russian)
6 Haddazh MH (2011) The formation of particlesin theheterophase radical polymerization of styrene [Obrazovaniye chastic pri radikalnoi geterofaznoi polimerizazyi stirola]. Abstract of dissertation for Doctor of Chemical Sciences Degree, Moscow, Russia. P.254. (In Russian)
7 Lobanova NA, Gritskova IA, Chalyh AE, Levachev SM, Lobanov AN (2015) Russian Chemical Bulletin 1:1-5. (In Russian)
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.
Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License (CC BY-NC-ND 4.0) that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.