Synthesis of a new complex borate KBaSm(BO3)2

  • Asset Kuanyshevich Bolatov al-Farabi Kazakh National University, Almaty
  • Alexander Egorovich Kokh V.S. Sobolev Institute of Geology and Mineralogy Siberian Branch Russian Academy of Sciences, Novosibirsk
  • Nadezhda Georgievna Kononova V.S. Sobolev Institute of Geology and Mineralogy Siberian Branch Russian Academy of Sciences, Novosibirsk
  • Vyacheslav Sergeevich Shevchenko V.S. Sobolev Institute of Geology and Mineralogy Siberian Branch Russian Academy of Sciences, Novosibirsk
  • Mukhambetkali Myrzabaevich Burkitbayev al-Farabi Kazakh National University, Almaty
  • Bolat Muratovich Uralbekov al-Farabi Kazakh National University, Almaty
  • Yerassyl Yerzhanuly Kaiyrzhan al-Farabi Kazakh National University, Almaty
DOI: https://doi.org/10.15328/cb687
Keywords: solid-state synthesis, complex orthoborate of rare earth element, samarium, unit cell parameters of crystalline lattice

Abstract

A novel compound containing three cation alkali, alkali earth, rare earth orthoborate KBaSm(BO3)2 was synthesized by using two-step solid-state method. Results of powder X-ray diffraction analysis (XRD) and FTIR spectroscopy showed that this compound is isostructural with known compounds KBaY(BO3)2 [1] and KBaTbB2O6 [2] and refers to trigonal crystal system (RǮm space group with unit cell parameters of crystalline lattice а=5,4845(10) Å, с=18,135(13), Z=3).
KBaSm(BO3)2 was obtained at a temperature of 825°C from initial reactants: samarium (III) oxide, barium and potassium carbonates and boric acid. Among KBaSm(BO3)2 – KBaTb(BO3)2 – KBaY (BO3)2 observed a regular linear variation of unit cell parameters, as well as regular shift of the bands in the IR spectra, depending on the size of the rare earth cation.

References

1 Gao J, Song L, Hu X, Zhang D (2011) Solid State Sci 13:115-119. http://dx.doi.org/10.1016/j.solidstatesciences.2010.10.021

2 Lian Zh, Sun J, Ma Zh, Zhang L, Shen D, Shen G, Wang X, Yan Q (2014) J Cryst Growth 401:334-337. http://dx.doi.org/10.1016/j.jcrysgro.2013.11.007

3 Tian L (2010) Journal of Rare Earths 28:37-39. http://dx.doi.org/10.1016/S1002-0721(09)60046-6

4 Gao JH, Li RK (2008) Mater Res Bull 43:882-888. http://dx.doi.org/10.1016/j.materresbull.2007.05.009

5 Gao JH, Li RK (2008) Solid State Sci 10:26-30. http://dx.doi.org/10.1016/j.solidstatesciences.2007.08.009

6 Seryotkin Y, Bakakin V, Kokh A, Kononova N, Svetlyakova T, Kokh K, Drebushchak T (2010) J Solid State Chem 183:1200-1204. http://dx.doi.org/10.1016/j.jssc.2010.03.005

7 Svetlyakova TN, Kokh AE, Kononova NG, Fedorov PP, Rashchenko SV, Maillard A (2013) Crystallogr Rep+ 58:54-60. http://dx.doi.org/10.1134/S1063774513010136

8 Lian Zh, Sun J, Zhang L, Shen D, Shen G, Wang X, Yan Q (2013) RSC Advances 3:16534-16541. http://dx.doi.org/10.1039/C3RA42380H

9 Han L, Wang Yu, Wang Ya, Zhang J, Tao Y (2013) J Alloy Compd 551:485-489. http://dx.doi.org/10.1016/j.jallcom.2012.11.01110

10   Peng Y, Lian Zh, Zhang L, Shen G, Wang X, Yan Q (2014) Materials Express 4:533-538. http://dx.doi.org/10.1166/mex.2014.1195

11   Svetlyakova TN, Kononova NG, Kokh AE, Kokh KA, Palchic NA (2011) Russ J Inorg Chem+ 56:117-121. (In Russian)

12   Pabst A (1974) Am Mineral 59:353-358.

13   Miura H (2003) Journal of the Crystallographic Society of Japan 45:145-147.

14   Dronskowski R (2005) Computational chemistry of solid state materials: A guide for materials scientists, chemists, physicists and others. Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, Germany. ISBN: 978-3-527-31410-2

15   Gautam C, Yadav AK, Singh AK (2012) International Scholarly Research Network ID428497. http://dx.doi.org/10.5402/2012/428497

16   Kurazhkovskaya VS, Borovikova YeYu, Leonyuk NI, Koporulina YeV, Belokoneva YeL (2008) J Struct Chem+ 49:1074-1080. (In Russian)

17   Borovikova EYu, Dobretsova EA, Boldyrev KN, Kurazhkovskaya VS, Maltsev VV, Leonyuk NI (2013) Vib Spectrosc 68:82-90. http://dx.doi.org/10.1016/j.vibspec.2013.05.004

Published
2016-03-30
How to Cite
Bolatov, A., Kokh, A., Kononova, N., Shevchenko, V., Burkitbayev, M., Uralbekov, B., & Kaiyrzhan, Y. (2016). Synthesis of a new complex borate KBaSm(BO3)2. Chemical Bulletin of Kazakh National University, 81(1), 50-57. https://doi.org/https://doi.org/10.15328/cb687
Issue
Vol 81 No 1 (2016): Chemical Bulletin of Kazakh National University
Section
Inorganic Chemistry
Creative Commons License

This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License (CC BY-NC-ND 4.0) that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.