Bimetallic Pd-Cu-composites of polyaniline in electrocatalytic hydrogenation of phenylacetylene

  • Elena Anatolievna Soboleva Institute of Organic Synthesis and Chemistry of Coal of Kazakhstan Republic, Karaganda
  • Yakha Akhmadovna Visurkhanova Institute of Organic Synthesis and Chemistry of Coal of Kazakhstan Republic, Karaganda
  • Nina Mikhailovna Ivanova Institute of Organic Synthesis and Chemistry of Coal of Kazakhstan Republic, Karaganda
Keywords: polyaniline; bimetallic Pd-Cu-composites; electrocatalytic hydrogenation; phenylacetylene; ethyl benzene; 1,4-diphenylbutane

Abstract

Bimetallic Pd-Cu-composites of polyaniline prepared by introducing metals (II) chlorides in the process of oxida-tive polymerization of aniline with and without chemical reduction by sodium borohydride are applied to copper cath-ode activation in electrohydrogenation of phenylacetylene in basic aqueous ethanolic solutions of catholyte. Electro-catalytic activity of composites that they exhibited in the process is due to formation of metal particles (and their al-loys) by electrochemical reduction of metal cations in the polymer matrix. The main hydrogenation products are ethyl benzene and 1,4-diphenylbutane, the yields of which influence metal content in the studied composites.

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Published
2017-03-31
How to Cite
Soboleva, E., Visurkhanova, Y., & Ivanova, N. (2017). Bimetallic Pd-Cu-composites of polyaniline in electrocatalytic hydrogenation of phenylacetylene. Chemical Bulletin of Kazakh National University, 84(1), 4-14. https://doi.org/https://doi.org/10.15328/cb773
Section
Physical Chemistry and Electrochemistry