Bimetallic Pd-Cu-composites of polyaniline in electrocatalytic hydrogenation of phenylacetylene
Abstract
Bimetallic Pd-Cu-composites of polyaniline prepared by introducing metals (II) chlorides in the process of oxida-tive polymerization of aniline with and without chemical reduction by sodium borohydride are applied to copper cath-ode activation in electrohydrogenation of phenylacetylene in basic aqueous ethanolic solutions of catholyte. Electro-catalytic activity of composites that they exhibited in the process is due to formation of metal particles (and their al-loys) by electrochemical reduction of metal cations in the polymer matrix. The main hydrogenation products are ethyl benzene and 1,4-diphenylbutane, the yields of which influence metal content in the studied composites.
References
2 Feng J, Liu Y, Yin M, He Y, Zhao J Sun J, Li D (2016) J Catal 344:854-864. Crossref
3 Rai RK, Gupta K, Tyagi D, Mahata A, Behrens S, Yang X, Xu Q, Pathak B, Singh SK (2016) Catalysis Science & Technology 6:5567-5579. Crossref
6 Maksimov YuM, Kolyadko EA, Shishlova AV, Podlovchenko BI (2001) Russ J Electrochem+ 37:777-781. Crossref
7 (2005) Metal-polymer nanocomposites (formation, properties, application) / Ed. Lyakhov NC [Metallopolimernyye nanokompozity (polucheniye, svoystva, primeneniye)]. Siberian Branch of Russian Academy of Sciences, Novosibirsk, Russia. (In Russian). ISBN 5-7692-0669-1
8 Yashtulov NA, Bolshakova AN, Flid VR, Revina АА (2011) Theor Found Chem Eng 6:54-58. (In Russian)
9 Sarkany A, Hargittai P, Horvath A (2007) Top Catal 46:121-128. Crossref
10 Coq B, Figueras F (2001) J Mol Catal A-Chem 173:117-134. Crossref
11 Gubin SP (2006) Russ J Gen Chem 50:46-54. (In Russian)
12 Singh AK, Xu Q (2013) ChemCatChem 5:652-676. Crossref
13 Ellert OG, Tsodikov MV, Nikolaev SA, Novotortsev VM (2014) Russ Chem Rev 83:718-732. Crossref
14 Nikolaev SA, Zanaveskin LN, Smirnov VV, Averyanov VA, Zanaveskin KL (2009) Russ Chem Rev 78:231-248. Crossref
15 Nikolaev SA, Krotova IN (2013) Petrol Chem+ 53:442-448. (In Russian)
16 Tyurina LA, Nikolaev SA, Gurevich SA, Kozhevin VM, Smirnov VV, Zanaveskin KL (2008) Catalysis in Industry Special Issue:86-91. (In Russian).
17 Oosthuizen RS, Nyamori VO (2011) Platin Met Rev 55:154-169. Crossref
18 Kosydar R, Goral M, Drelinkiewicz A, Stejskal Ja (2013) Chem Pap 67:1087-1095. Crossref
19 Vatsulik P (1960) Chemistry of monomers. Part 1 [Khimiya monomerov]. Foreign Literature Pub-lishing House, Moscow, USSR. (In Russian)
20 Tomilov АP, Mairanovskii МYa, Fioshin МYa, Smirnov VА (1968) Electrochemistry of organic compounds [Elektrokhimiya organicheskikh veshchestv]. Chemistry, Leningrad, USSR. (In Russian)
21 Ivanova NM, Soboleva EA, Izbastenova DS, Visurkhanova YaA, Tusupbekova GK (2014) Patent 29408 Republic of Kazakhstan. Application of composites on the base of polyaniline and metal salts for activating the cathode in the processes of electrohydrogenation of organic compounds [Prime-neniye kompozitov na osnove polianilina i soley metallov dlya vosstanovleniya katoda v protsesse elektrogidrirovaniya organicheskikh soyedineniy].
22 Ivanova NM, Izbastenova DS, Visurkhanova YaA, Kirilyus IV (2014) KazNU Chem Bull 2:3-12. (In Russian). Crossref
23 Ivanova NM, Soboleva EA, Visurkhanova YaA, Kirilyus IV (2015) Russ J Electrochem+ 51:166-173. Crossref
24 Stejskal J, Gilbert RG (2002) Pure Appl Chem 74:857-867. Crossref
25 Yurist IM, Talmud ММ (1993) Selective complexometric titration [Selektivnoye kompleksono-metricheskoye titrovaniye]. Nauka, Moscow, Russia. (In Russian)
26 Sun Z, Geng Ya, Li J, Jing X, Wang F (1997) Synthetic Met 84:99-100. Crossref
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