Synthesis and characterization of novel acrylamide-based ternary polyampholyte as tracer agent

  • Iskander Gussenov Institute of Polymer Materials and Technologies, 1/3 microdistrict “Atyrau 1”, Almaty 050019, Kazakhstan
  • Nurbatyr Mukhametgazy Institute of Polymer Materials and Technologies, 1/3 microdistrict “Atyrau 1”, Almaty 050019, Kazakhstan; Satbayev University, 22a Satpaev str., Almaty 050013, Kazakhstan
  • Alexey V. Shakhvorostov Institute of Polymer Materials and Technologies, 1/3 microdistrict “Atyrau 1”, Almaty 050019, Kazakhstan https://orcid.org/0000-0003-3502-6123
  • Sarkyt E. Kudaibergenov Institute of Polymer Materials and Technologies, 1/3 microdistrict “Atyrau 1”, Almaty 050019, Kazakhstan https://orcid.org/0000-0002-1166-7826
Keywords: ternary polyampholyte, synthesis, characterization, core flooding, filtration, tracer

Abstract

A novel ternary polyampholyte composed of fully charged anionic monomer – 2-acrylamido-2-methyl-1-propanesulfonic acid sodium salt (AMPS), cationic monomer – (3-acrylamidopropyl) trimethylammonium chloride (APTAC) and the positively charged fluorescent dye – acrylamide Nile Blue (ANB) was synthesized by conventional free radical copolymerization and characterized by FTIR, UV-Vis, fluorescence spectroscopy, dynamic light scattering and zeta-potential. FTIR spectrum of AMPS-APTAC-ANB shows that introduction of 1 mol.% ANB into copolymer composition does not influence the basic characteristic bands of polyampholyte. The adsorption and emission peaks of AMPS-APTAC-ANB found at lmax = 586 nm and lmax = 660-680 nm are attributed to ANB groups of terpolymer. The average hydrodynamic size and zeta potential of AMPS-APTAC-ANB in aqueous solution that are equal to 4.3 nm and x= -1.6 mV indicating the globular conformation of amphoteric macromolecules with a slightly negative charge. Injection of 0.1 wt.% (or 1.3×10-3 mol×L-1) AMPS-APTAC-ANB into the core sample derived from the “Vostochnyi Moldabek” oilfield demonstrated the passing of fluorescently-labeled terpolymer through the core. The ternary polyampholyte containing the fluorescent marker can serve as oilfield tracer for monitoring well-to-well connections (or interwell tracer test).

References

1 Kudaibergenov SE (2002) Polyampholytes: Synthesis, Characterization and Application. Springer, New York. ISBN: 978-1-4615-0627-0

2 Lowe AB, McCormick CL (2002) Chem Rev 102(11): 4177-4190. Crossref

3 Kudaibergenov S, Okay O (2020) Polym Advan Technol Special Issue Review:1-16. Crossref

4 Toleutay G, Shakhvorostov A, Kabdrakhmanova S, Kudaibergenov S (2019) Chemistry Series 2(94): 35-44. Crossref

5 Toleutay G, Su E, Kudaibergenov S (2019) Bulletin of the Karaganda University, Chemistry Series 4(96):35-43.

6 Toleutay G, Dauletbekova M, Shakhvorostov A, Kudaibergenov S (2019) Macromol Symp 385:1800160. Crossref

7 Toleutay G, Su E, Kudaibergenov S, Okay O (2020) Colloid Polym Sci 298: 273-284. Crossref

8 Mukhametgazy N, Gussenov I, Shakhvorostov A (2019) AIP Conference Proceedings 2167:020236. Crossref

9 Mukhametgazy N, Gussenov I, Shakhvorostov A, Kudaibergenov S (2020) Bulletin of the Karaganda University, Chemistry Series 4(100):119-127. Crossref

10 Kudaibergenov S, Gussenov I, Shakhvorostov A (2020) Method for production of fluorescent polymer tracer. Patent for utility model of the Republic of Kazakhstan No. 5723. Filed from 14.10.2020.

11 Serres-Piole C, Preud’homme H, Moradi-Tehrani N, Allanic C, Jullia H, Lobinski R (2012) J Petrol Sci Eng 98-99:22-39. Crossref

12 Konev DA (2014) Modern high technologies [Sovremennye nauloemkie tehnologii] 7(2):23-26. (In Russian)

13 Kang WL, Hu LL, Zhang XF, Yang RM, Fan HM, Geng J (2015) Pet Sci 12:483-491. Crossref

14 Yan L, Yin T, Yu W, Shen L, Lv M, Ye Z (2015) RSC Adv 5:42843-42847. Crossref

15 Yang H, Hu L, Chen C, Gao Y, Tang X, Yin X, Kang W (2018) RSC Adv 8:10478-10488. Crossref
Published
2021-03-19
How to Cite
Gussenov, I., Mukhametgazy, N., Shakhvorostov, A., & Kudaibergenov, S. (2021). Synthesis and characterization of novel acrylamide-based ternary polyampholyte as tracer agent. Chemical Bulletin of Kazakh National University, 100(1), 22-29. https://doi.org/https://doi.org/10.15328/cb1183