Study of the structure of radiation-grafted vinyl ethers onto the matrix of oxidized atactic polypropylene, by 1H-NMR spectroscopy

  • S. Kenbeilova Kazakh National Technical University named after K.I. Satpaev, Almaty
  • Galina I. Boiko Kazakh National Technical University named after K.I. Satpaev, Almaty
  • Erengaip Shaikhutdinov Kazakh National Technical University named after K.I. Satpaev, Almaty
  • N. Lyubchenko HEE «Unat», Almaty
  • T. Maimakov HEE «Unat», Almaty
DOI: https://doi.org/10.15328/chemb_2013_275-80
Keywords: radiation grafting, oxidized atactic polypropylene, monovinyl ether of ethylene glycol, vinyl butyl ether

Abstract

The structure of graft copolymers synthesized by radiation grafting of vinyl ethers to the polymeric matrix of oxidized atactic polypropylene was determined by 1H-NMR spectroscopy. The most probable structure of the graft polymers was determined, and it is shown that grafting is carried out on the tertiary carbon atom of the macromolecule. The grafting degree of vinyl esters increases with increasing of exposure dose from 200 kGy to 1200 kGy.

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Published
2013-05-14
How to Cite
Kenbeilova, S., Boiko, G., Shaikhutdinov, E., Lyubchenko, N., & Maimakov, T. (2013). Study of the structure of radiation-grafted vinyl ethers onto the matrix of oxidized atactic polypropylene, by 1H-NMR spectroscopy. Chemical Bulletin of Kazakh National University, 70(2), 75-80. https://doi.org/https://doi.org/10.15328/chemb_2013_275-80
Issue
Vol 70 No 2 (2013): Chemical Bulletin of Kazakh National University
Section
Organic and Polymers Chemistry
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