The use of solid phase microextraction as sample preparation technique for determination of n-nitrosodimethylamine in water polluted by hydrazine-based rocket fuel

Abstract

A paper describes a method for determination of N-nitrosodimethylamine in water, polluted by spills of 1,1-dimethylhydrazine, based on solid phase microextraction coupled to gas chromatography/mass spectrometry. A method detection limit was determined to be 1 ug/kg, relative error was below 20%. A method is very sensitive and selective as well as quite simple, relatively cheap and fully automated.

References

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Cited by: 4

1. Kenessov B, Alimzhanova M, Sailaukhanuly Y, et al (2012) Transformation products of 1,1-dimethylhydrazine and their distribution in soils of fall places of rocket carriers in Central Kazakhstan. Science of the Total Environment 427-428: 78-85. CrossRef

2. Kosyakov DS, Ulyanovskii NV, Pokryshkin SA (2015) Rapid determination of 1,1-dimethylhydrazine transformation products in soil by accelerated solvent extraction coupled with gas chromatography–tandem mass spectrometry. Int J Environ Anal Chem 95:1321-1337. CrossRef

3. Kenessov BN, Batyrbekova SY (2012) Actual directions in study of ecological consequences of a highly toxic 1,1-dimethylhydrazine-based rocket fuel spills. Chemical Bulletin of Kazakh National University 2:124-131. CrossRef

4. Kenessov BN, Carlsen L (2014) Identification (quantitative determination and detection) and fate of transformation products of rocket fuel 1,1-dimethylhydrazine. In: Lambropoulou LA, Nollet ML (eds.) Transformation Products of Emerging Contaminants in the Environment: Analysis, Processes, Occurrence, Effects and Risks. CrossRef

Published
2009-05-15
How to Cite
KENESSOV, Bulat. The use of solid phase microextraction as sample preparation technique for determination of n-nitrosodimethylamine in water polluted by hydrazine-based rocket fuel. Chemical Bulletin of Kazakh National University, [S.l.], n. 2, p. 92-97, may 2009. ISSN 2312-7554. Available at: <https://chemistry.kz/bulletin/index.php/kaznu/article/view/147>. Date accessed: 19 oct. 2017. doi: https://doi.org/10.15328/chemb_2009_292-97.
Section
Analytical Chemistry

Keywords

N-nitrosodimethylamine; solid-phase microextraction; 1,1-dimethylhydrazine; gas chromatography; mass spectrometry; water